How to Make It
In a large saucepan, heat the olive oil until shimmering. Add the onion, leeks and a generous pinch each of salt and pepper. Cook over moderately high heat, stirring occasionally, until starting to brown, about 5 minutes. Add the carrots, thyme, ancho powder, paprika, cumin and chipotle powder and cook, stirring occasionally, until the carrots are softened and the spices are fragrant, 5 to 7 minutes. Add the mushrooms and cook, stirring, until starting to soften, about 3 minutes.
Stir in the barley, quinoa and wine and cook over moderate heat, stirring occasionally, until the wine is slightly reduced, about 5 minutes. Add the tomatoes with their juices and the vegetable broth and bring to a boil. Cover partially and simmer over moderately low heat, stirring occasionally, until slightly thickened and the grains are tender, about 45 minutes. Stir in the beans and simmer for 10 minutes longer, stirring occasionally. Ladle the chili into bowls and serve with chopped cilantro, thinly sliced scallions, shredded cheese and sour cream.