Between the andouille sausage and the cayenne, this is one spicy dish. With plenty of rice, vegetables, and chicken in the pot, it's also a satisfying dinner. If you can't find andouille and need to substitute a milder sausage, ...
The somewhat vegetal flavors of the Sauvignon Blanc grape will be right at home here. Try one from the United States (sometimes called Fumé Blanc). It will have enough richness to stand up to the sausage.